Journal article
Aspects of stereocontrol in the L-Selectride reduction of 4-acyl-1,3-dioxolane derivatives
- Abstract:
- The application of L-Selectride, either alone or in combination with ZnCl2, to aryl ketones 1, 8 and 11 resulted in highly anti-stereoselective reduction. In contrast, lactols 22 and 23 gave a moderate syn-preference using L-Selectride alone and a high syn-preference in the presence of ZnCl2. Uniquely, high anti- stereoselectivity was observed in the reduction of o-anisyl lactol 37 with L-Selectride alone, which was switched to a high syn-preference when ZnCl2 was present. © 2010 Elsevier Ltd. All rights reserved.
- Publication status:
- Published
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- Publisher copy:
- 10.1016/j.tet.2010.01.107
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Authors
Bibliographic Details
- Journal:
- TETRAHEDRON
- Volume:
- 66
- Issue:
- 13
- Pages:
- 2363-2372
- Publication date:
- 2010-03-27
- DOI:
- ISSN:
-
0040-4020
- Source identifiers:
-
55212
Item Description
- Language:
- English
- Keywords:
- Pubs id:
-
pubs:55212
- UUID:
-
uuid:118c78a3-5454-4c8c-9250-8f63a627dda5
- Local pid:
- pubs:55212
- Deposit date:
- 2012-12-19
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- Copyright date:
- 2010
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