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Journal article

Highly efficient ethylene polymerisation by scandium alkyls supported by neutral fac-kappa3 coordinated N3 donor ligands.

Abstract:
Reaction of [M(CH2SiMe3)3(THF)2] (M = Sc or Y) with the neutral fac-kappa3 N3 donor ligands (L) Me3[9]aneN3 or HC(Me2pz)3 gave the corresponding trialkyls [M(L)(CH2SiMe3)3]; activation of the scandium congeners with B(C6F5)3 in the presence of ethylene afforded highly active polymerisation catalysts (Me3[9]aneN3 = 1,4,7-trimethyltriazacyclononane).
Publication status:
Published

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Publisher copy:
10.1039/b310867h

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
Chemical Communications
Volume:
9
Issue:
23
Pages:
2880-2881
Publication date:
2003-12-01
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
Source identifiers:
51037
Language:
English
Pubs id:
pubs:51037
UUID:
uuid:1187c25d-9fbc-4dd1-a1dd-1f8d461b1ffa
Local pid:
pubs:51037
Deposit date:
2012-12-19

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