Journal article
Highly efficient ethylene polymerisation by scandium alkyls supported by neutral fac-kappa3 coordinated N3 donor ligands.
- Abstract:
- Reaction of [M(CH2SiMe3)3(THF)2] (M = Sc or Y) with the neutral fac-kappa3 N3 donor ligands (L) Me3[9]aneN3 or HC(Me2pz)3 gave the corresponding trialkyls [M(L)(CH2SiMe3)3]; activation of the scandium congeners with B(C6F5)3 in the presence of ethylene afforded highly active polymerisation catalysts (Me3[9]aneN3 = 1,4,7-trimethyltriazacyclononane).
- Publication status:
- Published
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- Publisher copy:
- 10.1039/b310867h
Authors
- Journal:
- Chemical Communications More from this journal
- Volume:
- 9
- Issue:
- 23
- Pages:
- 2880-2881
- Publication date:
- 2003-12-01
- DOI:
- EISSN:
-
1364-548X
- ISSN:
-
1359-7345
- Language:
-
English
- Pubs id:
-
pubs:51037
- UUID:
-
uuid:1187c25d-9fbc-4dd1-a1dd-1f8d461b1ffa
- Local pid:
-
pubs:51037
- Source identifiers:
-
51037
- Deposit date:
-
2012-12-19
- ARK identifier:
Terms of use
- Copyright date:
- 2003
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