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Copper complexation in coastal rainwater, southeastern USA

Abstract:

Complexation of dissolved copper (Cu) was studied in Atlantic coastal rainwater using adsorptive cathodic stripping voltammetry (ASCV) with salicylaldoxime as a competing ligand at pH 7.8. Detectable concentrations of strong Cu-complexing ligands possessing conditional stability constants of 1013-1016 were observed in over 80% of the rain events occurring over the course of 2 year. In 11 of the 23 samples analysed, total dissolved Cu concentrations were higher than those of dissolved ligands,...

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Publication status:
Published

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Institution:
University of Oxford
Division:
MPLS
Department:
Earth Sciences
Role:
Author
Journal:
ATMOSPHERIC ENVIRONMENT
Volume:
41
Issue:
17
Pages:
3619-3630
Publication date:
2007-06-01
DOI:
ISSN:
1352-2310
Source identifiers:
166382
Language:
English
Keywords:
Pubs id:
pubs:166382
UUID:
uuid:1180fd7d-1b57-4267-b095-b95271fbc855
Local pid:
pubs:166382
Deposit date:
2012-12-19

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