Journal article

Synthesis of new [1(4)]metallocenophanes

Abstract:: Vilsmeier formylation of the trimetallic species {(C5Me4H)Fe(C5Me4)CH 2C5H4}2Fe (1) gives {(C5Me4CHO)Fe(C5Me4)CH 2C5H4}2Fe (2) and a triformylated product 3, the structure of which has been established by a 1H:1H NOESY experiment. 2 can be converted, by three additional steps, to the new [14]ferrocenophane, (C5H4CH2C5Me4) 4Fe4 (8), in which ferrocene and permethylated ferrocene units alternate. The methodology also permits the synthesis of heteronuclear species comprising two permethylated ferrocenylene units, a ferrocenylene unit, and a heterometallocenylene; thus, {(C5H4CH2C5Me4) 4Fe3Co}+PF6 - (10) has been characterized.

Publication status:: Published

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APA Style

Barlow, S., & OHare, D. (1996). Synthesis of new [1(4)]metallocenophanes. ORGANOMETALLICS, 15(18), 3885–3890.

MLA Style

Barlow, S., and D. OHare. “Synthesis of New [1(4)]Metallocenophanes.” ORGANOMETALLICS, vol. 15, no. 18, 1996, pp. 3885–90.

Chicago Style

Barlow, S, and D OHare. 1996. “Synthesis of New [1(4)]Metallocenophanes.” ORGANOMETALLICS 15 (18): 3885–90.
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Publisher copy:: 10.1021/om960227w

Authors

+ Barlow, S More by this author

Role:: Author

+ OHare, D More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

Journal:: ORGANOMETALLICS More from this journal
Volume:: 15
Issue:: 18
Pages:: 3885-3890
Publication date:: 1996-09-03
DOI:: 10.1021/om960227w
EISSN:: 1520-6041
ISSN:: 0276-7333

Pubs id:: pubs:51456
UUID:: uuid:1139bc15-9f56-4950-98c5-d36a6db29d5c
Local pid:: pubs:51456
Source identifiers:: 51456
Deposit date:: 2012-12-19

Terms of use

Copyright date:: 1996

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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