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Infrared-induced reactivity of N2O on small gas-phase rhodium clusters.

Abstract:

Far- and mid-infrared multiple photon dissociation spectroscopy has been employed to study both the structure and surface reactivity of isolated cationic rhodium clusters with surface-adsorbed nitrous oxide, Rh(n)N(2)O(+) (n = 4-8). Comparison of experimental spectra recorded using the argon atom tagging method with those calculated using density functional theory (DFT) reveals that the nitrous oxide is molecularly bound on the rhodium cluster via the terminal N-atom. Binding is thought to oc...

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Publication status:
Published

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Publisher copy:
10.1021/jp201171p

Authors


Hamilton, SM More by this author
Hopkins, WS More by this author
Harding, DJ More by this author
Haertelt, M More by this author
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Journal:
The journal of physical chemistry. A
Volume:
115
Issue:
12
Pages:
2489-2497
Publication date:
2011-03-10
DOI:
EISSN:
1520-5215
ISSN:
1089-5639
URN:
uuid:111d5454-32ac-481a-a53e-98568887fcd2
Source identifiers:
124348
Local pid:
pubs:124348
Language:
English

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