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QUENCHING OF C2(API-3(PI-U)) PRODUCED IN AN INTENSE INFRARED-LASER FIELD

Abstract:
C2(a 3Πu) has been produced in the multiple-photon dissociation of acrylonitrile, C2H3CN, by a TEA CO2 laser. Laser-induced fluorescence has been used to determine time-resolved relative C2 concentrations in the presence of added Ar and O2 and second-order rate constants of 2 × 10-15 and 3.4 × 10-12 cm3 molecule-1 5-1 have been obtained for these two quenchers, respectively. Vacuum-ultraviolet chemiluminescence is observed in the quenching by O2. © 1979.
Publication status:
Published

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
Journal:
CHEMICAL PHYSICS LETTERS
Volume:
61
Issue:
2
Pages:
288-292
Publication date:
1979-01-01
DOI:
ISSN:
0009-2614
URN:
uuid:10ef4b79-388b-43f3-a306-7ebbbd2cfa54
Source identifiers:
41844
Local pid:
pubs:41844
Language:
English

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