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Perfect quintuple layer Bi₂Te₃ nanowires: Growth and thermoelectric properties

Abstract:
Bi2Te3 nanowires are promising candidates for thermoelectric applications. Vapor-liquid-solid growth of these nanowires is straightforward, but the traditional Au-catalyzed method is expected to lead to Au contamination and subsequently crystal defects. Here, we present a comparison of the Au-catalyzed growth method with an alternative method using TiO2. We observe that the latter approach results in perfect quintuple layer nanowires, whilst using Au leads to mixed quintuple and septuple layer structures. Despite these differences, we surprisingly find only a negligible effect on their thermoelectric properties, namely conductivity and Seebeck coefficient. This result is relevant for the further optimization and engineering of thermoelectric nanomaterials for device applications.
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1063/1.4986524

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Physics
Sub department:
Condensed Matter Physics
Role:
Author


Publisher:
American Institute of Physics
Journal:
APL Materials More from this journal
Volume:
5
Pages:
086110
Publication date:
2017-08-01
Acceptance date:
2017-08-10
DOI:
EISSN:
2166-532X


Keywords:
Pubs id:
pubs:713168
UUID:
uuid:10c539dd-87a8-4262-8d81-2811b7b7e925
Local pid:
pubs:713168
Source identifiers:
713168
Deposit date:
2017-08-10

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