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A chiral ferromagnetic molecular metal.

Abstract:
The first molecular material with the coexistence of ferromagnetism, metal-like conductivity, and chirality has been prepared using an organic/inorganic approach. In this case, a two-dimensional packing of chiral organic radical cations (responsible for both the electrical conductivity and optical activity) was assembled with a layered bimetallic oxalate-based anionic network (responsible for the magnetic properties). Shubnikov-de Haas oscillations confirmed the presence of a Fermi surface even when the transport properties suggested "insulating"-type behavior at very low temperatures.
Publication status:
Published

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Publisher copy:
10.1021/ja103147k

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Physics
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Physics
Sub department:
Condensed Matter Physics
Role:
Author


Journal:
Journal of the American Chemical Society More from this journal
Volume:
132
Issue:
27
Pages:
9271-9273
Publication date:
2010-07-01
DOI:
EISSN:
1520-5126
ISSN:
0002-7863


Language:
English
Pubs id:
pubs:156023
UUID:
uuid:10c40f78-2bb6-4bd5-8b0b-037987067887
Local pid:
pubs:156023
Source identifiers:
156023
Deposit date:
2012-12-19

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