Journal article
Reversible encapsulation of xenon and CH2Cl2 in a solid-state molecular organometallic framework (Guest@SMOM)
- Abstract:
- Reversible encapsulation of CH 2 Cl 2 or Xe in a non–porous solid–state molecular organometallic framework of [Rh(Cy 2 PCH 2 PCy 2 )(NBD)][BAr F 4 ] occurs in single–crystal to single–crystal transformations. These processes are also probed by solid–state NMR spectroscopy, including 129 Xe SSNMR. Non–covalent interactions with the –CF 3 groups, and hydrophobic channels formed, of [BAr F 4 ] – anions are shown to be important, and thus have similarly to the transport of substrates and products to and from the active site in metalloenzymes.
- Publication status:
- Published
- Peer review status:
- Peer reviewed
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(Preview, Version of record, 3.3MB, Terms of use)
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- Publisher copy:
- 10.1002/anie.201910539
Authors
- Publisher:
- Wiley
- Journal:
- Angewandte Chemie International Edition More from this journal
- Volume:
- 58
- Issue:
- 47
- Pages:
- 16873-16877
- Publication date:
- 2019-09-20
- Acceptance date:
- 2019-09-20
- DOI:
- ISSN:
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1521-3773
- Language:
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English
- Keywords:
- Pubs id:
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pubs:1054481
- UUID:
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uuid:10bc8753-78f1-4488-9010-eaf654b1285b
- Local pid:
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pubs:1054481
- Source identifiers:
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1054481
- Deposit date:
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2019-09-20
Terms of use
- Copyright holder:
- Martínez‐Martínez, Rees, and Weller
- Copyright date:
- 2019
- Rights statement:
- © 2019 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution License
- Notes:
- This is an open access article distributed under the terms of the Creative Commons Attribution Licence
- Licence:
- CC Attribution (CC BY)
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