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Fluorescent cyclic voltammetry of immobilized azurin: direct observation of thermodynamic and kinetic heterogeneity.

Abstract:

(Figure Presented) Variations in the formal electrochemical potential (E 0) and electron-transfer rates (K 0) of the blue copper protein azurin have been directly observed. A new method, fluorescent cyclic voltammetry (FCV), was used to resolve the properties of 100-1000 proteins. On this scale, the presence of large variations in the values of both E 0 and k 0 could be established and several form...

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Publication status:
Published

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Publisher copy:
10.1002/anie.201001298

Authors


Salverda, JM More by this author
Kuznetsova, S More by this author
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Journal:
Angewandte Chemie (International ed. in English)
Volume:
49
Issue:
33
Pages:
5776-5779
Publication date:
2010-08-05
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
URN:
uuid:104d8448-1b59-4f31-a127-288d5d6a3620
Source identifiers:
71226
Local pid:
pubs:71226

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