Journal article

Dehydrogenation of cyclohexenes to cyclohexadienes by [(PPh3)(2)Rh](+). The isolation of an intermediate in the dehydrogenation of cyclohexane to benzene: crystal structure of [(eta(4)-C6H8)Rh(PPh3)(2)][closo-CB11H6Br6]

Abstract:: Treatment of the arene bridged dimer [(PPh3)2Rh]2 [closo-CB11H6Br6]2 with eight equivalents of cyclohexene affords [(η4- C6H8) Rh(PPh3)2] [closo-CB11H6Br6] with the concomitant formation of one equivalent of cyclohexane, while 1-methylcyclohexane and 4-methylcyclohexane both give 2-methylcyclohexa-1,3-diene complexes; all of these products are intermediates in the catalytic dehydrogenation pathway of cyclohexane to benzene. © 2002 Elsevier Science B.V. All rights reserved.

Publication status:: Published

Actions

Email

Email this record

Send the bibliographic details of this record to your email address.

Your Email
Please enter the email address that the record information will be sent to.

-
Your message (optional)
Please add any additional information to be included within the email.
Share
Cite

Cite this record

APA Style

Rifat, A., Mahon, M., & Weller, A. (2003). Dehydrogenation of cyclohexenes to cyclohexadienes by [(PPh3)(2)Rh](+). The isolation of an intermediate in the dehydrogenation of cyclohexane to benzene: crystal structure of [(eta(4)-C6H8)Rh(PPh3)(2)][closo-CB11H6Br6]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 667(1-2), 1–4.

MLA Style

Rifat, A, et al. “Dehydrogenation of Cyclohexenes to Cyclohexadienes by [(PPh3)(2)Rh](+). The Isolation of an Intermediate in the Dehydrogenation of Cyclohexane to Benzene: Crystal Structure of [(Eta(4)-C6H8)Rh(PPh3)(2)][Closo-CB11H6Br6].” JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol. 667, nos. 1-2, 2003, pp. 1–4.

Chicago Style

Rifat, A, M Mahon, and A Weller. 2003. “Dehydrogenation of Cyclohexenes to Cyclohexadienes by [(PPh3)(2)Rh](+). The Isolation of an Intermediate in the Dehydrogenation of Cyclohexane to Benzene: Crystal Structure of [(Eta(4)-C6H8)Rh(PPh3)(2)][Closo-CB11H6Br6].” JOURNAL OF ORGANOMETALLIC CHEMISTRY 667 (1-2): 1–4.
Print

Access Document

Publisher copy:: 10.1016/S0022-328X(02)01923-X

Authors

+ Rifat, A More by this author

Role:: Author

+ Mahon, M More by this author

Role:: Author

+ Weller, A More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

Journal:: JOURNAL OF ORGANOMETALLIC CHEMISTRY More from this journal
Volume:: 667
Issue:: 1-2
Pages:: 1-4
Publication date:: 2003-02-03
DOI:: 10.1016/S0022-328X(02)01923-X
ISSN:: 0022-328X

Language:: English
Keywords:: rhodium

cyclohexene

dehydrogenation

C-H activation

X-ray structure
Pubs id:: pubs:51712
UUID:: uuid:0fe124b6-cd19-4183-8c6f-6a9731267f11
Local pid:: pubs:51712
Source identifiers:: 51712
Deposit date:: 2012-12-19
ARK identifier:: ark:/29072/ora_0fe124b6cd1941838c6f6a9731267f11

Terms of use

Copyright date:: 2003

Licence:: Terms and Conditions of Use for Oxford University Research Archive

Views and Downloads

About views and downloads

If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP