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The reaction products of the 193 nm photolysis of vinyl bromide and vinyl chloride studied by time-resolved Fourier transform infrared emission spectroscopy.

Abstract:

Time-resolved Fourier transform infrared (TRFTIR) emission spectroscopy has been used to study the 193 nm photolysis of vinyl bromide (C(2)H(3)Br) and vinyl chloride (C(2)H(3)Cl). Time-resolved IR emission was analysed to obtain nascent vibrational state populations of two primary photolysis products: HBr (v = 1-7) and HCl (v = 1-6). In both cases the nascent vibrational state populations monotonically decrease with increasing v and are in excellent agreement with previously published data. T...

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Publication status:
Published

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Publisher copy:
10.1039/b607882f

Authors


Carvalho, A More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Saunders, M More by this author
Journal:
Physical chemistry chemical physics : PCCP
Volume:
8
Issue:
37
Pages:
4337-4346
Publication date:
2006-10-05
DOI:
EISSN:
1463-9084
ISSN:
1463-9076
URN:
uuid:0f38634f-a35f-4cbb-bae6-6175582a2c2c
Source identifiers:
33603
Local pid:
pubs:33603
Language:
English

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