Journal article

ASYMMETRIC-SYNTHESIS OF 2-ARYL-TETRAHYDROPYRANS VIA ARENE CHROMIUM TRICARBONYL METHODOLOGY .2. 2-ARYL-3-ETHYL-4-CHLORO-TETRAHYDROPYRANS

Abstract:: Treatment of acetals derived from o-tolualdehyde chromium tricarbonyl and o-anisaldehyde chromium tricarbonyl with Z- and E-hex-3-en-1-ol and titanium tetrachloride generated, after decomplexation, completely stereoselectively the corresponding r-2-o-aryl-c-3-ethyl-c-4-chloro-tetrahydropyrans and r-2-o-aryl-c-3-ethyl-c-4-chloro-tetrahydropyrans respectively. This methodology was applied to the asymmetric synthesis of homochiral (R,R,S)- and (S,R,R)-2-o-anisyl-3-ethyl-4-chloro-tetrahydropyran from homochiral o-anisaldehyde chromium tricarbonyl and Z- and E-hex-3-en-1-ol respectively. © 1991.

Publication status:: Published

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APA Style

Davies, S., Donohoe, T., & Lister, M. (1991). ASYMMETRIC-SYNTHESIS OF 2-ARYL-TETRAHYDROPYRANS VIA ARENE CHROMIUM TRICARBONYL METHODOLOGY .2. 2-ARYL-3-ETHYL-4-CHLORO-TETRAHYDROPYRANS. TETRAHEDRON-ASYMMETRY, 2(11), 1089–1092.

MLA Style

Davies, S, et al. “ASYMMETRIC-SYNTHESIS OF 2-ARYL-TETRAHYDROPYRANS VIA ARENE CHROMIUM TRICARBONYL METHODOLOGY .2. 2-ARYL-3-ETHYL-4-CHLORO-TETRAHYDROPYRANS.” TETRAHEDRON-ASYMMETRY, vol. 2, no. 11, 1991, pp. 1089–92.

Chicago Style

Davies, S, T Donohoe, and M Lister. 1991. “ASYMMETRIC-SYNTHESIS OF 2-ARYL-TETRAHYDROPYRANS VIA ARENE CHROMIUM TRICARBONYL METHODOLOGY .2. 2-ARYL-3-ETHYL-4-CHLORO-TETRAHYDROPYRANS.” TETRAHEDRON-ASYMMETRY 2 (11): 1089–92.
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Publisher copy:: 10.1016/S0957-4166(00)82003-0

Authors

+ Davies, S More by this author

Role:: Author

+ Donohoe, T More by this author

Role:: Author

+ Lister, M More by this author

Role:: Author

Journal:: TETRAHEDRON-ASYMMETRY More from this journal
Volume:: 2
Issue:: 11
Pages:: 1089-1092
Publication date:: 1991-01-01
DOI:: 10.1016/S0957-4166(00)82003-0
EISSN:: 1362-511X
ISSN:: 0957-4166

Language:: English
Pubs id:: pubs:43771
UUID:: uuid:0f1324de-60d5-44cd-8e19-1c6c1486ed5f
Local pid:: pubs:43771
Source identifiers:: 43771
Deposit date:: 2012-12-19
ARK identifier:: ark:/29072/ora_0f1324de60d544cd8e191c6c1486ed5f

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Copyright date:: 1991

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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