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Nanoporosity and exceptional negative thermal expansion in single-network cadmium cyanide.

Abstract:
Accentuate the negative: Single-network cadmium cyanide displays isotropic negative thermal expansion behavior of unprecedented magnitude over a large temperature range (see graph of unit cell parameter a versus temperature). Guest molecules in the pores of this framework block the transverse vibrational modes responsible for this behavior, causing the value of the linear coefficient of thermal expansion to increase with guest occupancy. (Graph Presented) © 2008 Wiley-VCH Verlag GmbH and Co. KGaA.
Publication status:
Published

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Publisher copy:
10.1002/anie.200704421

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Journal:
Angewandte Chemie (International ed. in English) More from this journal
Volume:
47
Issue:
8
Pages:
1396-1399
Publication date:
2008-01-01
DOI:
EISSN:
1521-3773
ISSN:
1433-7851


Language:
English
Keywords:
Pubs id:
pubs:50523
UUID:
uuid:0ef96c68-a774-4ba3-bae4-f99cca439b91
Local pid:
pubs:50523
Source identifiers:
50523
Deposit date:
2012-12-19
ARK identifier:

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