Journal article
Nanoporosity and exceptional negative thermal expansion in single-network cadmium cyanide.
- Abstract:
- Accentuate the negative: Single-network cadmium cyanide displays isotropic negative thermal expansion behavior of unprecedented magnitude over a large temperature range (see graph of unit cell parameter a versus temperature). Guest molecules in the pores of this framework block the transverse vibrational modes responsible for this behavior, causing the value of the linear coefficient of thermal expansion to increase with guest occupancy. (Graph Presented) © 2008 Wiley-VCH Verlag GmbH and Co. KGaA.
- Publication status:
- Published
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- Publisher copy:
- 10.1002/anie.200704421
Authors
- Journal:
- Angewandte Chemie (International ed. in English) More from this journal
- Volume:
- 47
- Issue:
- 8
- Pages:
- 1396-1399
- Publication date:
- 2008-01-01
- DOI:
- EISSN:
-
1521-3773
- ISSN:
-
1433-7851
- Language:
-
English
- Keywords:
- Pubs id:
-
pubs:50523
- UUID:
-
uuid:0ef96c68-a774-4ba3-bae4-f99cca439b91
- Local pid:
-
pubs:50523
- Source identifiers:
-
50523
- Deposit date:
-
2012-12-19
- ARK identifier:
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- Copyright date:
- 2008
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