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Single-molecule kinetics of two-step divalent cation chelation.

Abstract:
A double hug: Two half-chelating ligands were covalently attached within the lumen of a protein nanopore (see picture). By electrical recording, the formation of fully chelated Zn 2+ ions was monitored at the single-molecule level, thus revealing the rate constants for the eight major steps in the process. Figure Equotion Present. © 2010 Wiley-VCH Verlag GmbH and Co. KGaA.
Publication status:
Published

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Publisher copy:
10.1002/anie.200906601

Authors


Hammerstein, AF More by this author
Journal:
Angewandte Chemie (International ed. in English)
Volume:
49
Issue:
30
Pages:
5085-5090
Publication date:
2010-07-05
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
URN:
uuid:0eae5d47-94fa-4eb3-9e19-367ed8c4cf15
Source identifiers:
60723
Local pid:
pubs:60723

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