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PHOTOELECTRON-SPECTRA OF METAL TETRAHYDROBORATES

Abstract:
Helium-(I) and -(II) excited photoelectron spectra of the metal tetrakis(tetrahydroborates) M(BH4)4 (M = Zr, Hf, or U) and the He(I) spectrum of Al(BH4)3 are reported. A simple molecular-orbital model is developed to account for features in the spectra associated with ligand ionizations. Final-state structure and cross-section variations for the outermost metal f subshells in U(BH4)4 and Hf(BH4)4 are discussed in relation to the expected atomic behaviour.
Publication status:
Published

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Publisher copy:
10.1039/dt9780001755

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Journal:
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS More from this journal
Issue:
12
Pages:
1755-1761
Publication date:
1978-01-01
DOI:
EISSN:
1364-5447
ISSN:
0300-9246


Language:
English
Pubs id:
pubs:41690
UUID:
uuid:0ea26624-370a-4171-a20b-76c858619fda
Local pid:
pubs:41690
Source identifiers:
41690
Deposit date:
2012-12-19
ARK identifier:

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