Journal article
PHOTOELECTRON-SPECTRA OF METAL TETRAHYDROBORATES
- Abstract:
- Helium-(I) and -(II) excited photoelectron spectra of the metal tetrakis(tetrahydroborates) M(BH4)4 (M = Zr, Hf, or U) and the He(I) spectrum of Al(BH4)3 are reported. A simple molecular-orbital model is developed to account for features in the spectra associated with ligand ionizations. Final-state structure and cross-section variations for the outermost metal f subshells in U(BH4)4 and Hf(BH4)4 are discussed in relation to the expected atomic behaviour.
- Publication status:
- Published
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- Publisher copy:
- 10.1039/dt9780001755
Authors
- Journal:
- JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS More from this journal
- Issue:
- 12
- Pages:
- 1755-1761
- Publication date:
- 1978-01-01
- DOI:
- EISSN:
-
1364-5447
- ISSN:
-
0300-9246
- Language:
-
English
- Pubs id:
-
pubs:41690
- UUID:
-
uuid:0ea26624-370a-4171-a20b-76c858619fda
- Local pid:
-
pubs:41690
- Source identifiers:
-
41690
- Deposit date:
-
2012-12-19
- ARK identifier:
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- Copyright date:
- 1978
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