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Enabling and probing oxidative addition and reductive elimination at a group 14 metal center: cleavage and functionalization of E-H bonds by a bis(boryl)stannylene

Abstract:

By employing strongly σ-donating boryl ancillary ligands, the oxidative addition of H2 to a single site Sn(II) system has been achieved for the first time, generating (boryl)2SnH2. Similar chemistry can also be achieved for protic and hydridic E-H bonds (N-H/O-H, Si-H/B-H, respectively). In the case of ammonia (and water, albeit more slowly), E-H oxidative addition can be shown to be followed by reductive elimination to give an N- (or O-)borylated product. Thus, in stoichiometric fashion, red...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Publisher's version

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Publisher copy:
10.1021/jacs.6b00710

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Publisher:
American Chemical Society Publisher's website
Journal:
Journal of the American Chemical Society Journal website
Volume:
138
Issue:
13
Pages:
4555-4564
Publication date:
2016-04-05
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
URN:
uuid:0e983fda-6c9e-4fad-8b70-8efadbd66889
Source identifiers:
611776
Local pid:
pubs:611776
Paper number:
13
Language:
English
Keywords:

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