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Titanium tert-butoxyimido compounds.

Abstract:

The synthesis and molecular and electronic structures of the first tert-butoxyimido complexes of titanium (TiNO(t)Bu functional group) are reported, featuring a variety of mono- or poly-dentate, neutral or anionic N-donor ligands. Reaction of Ti(NMe(2))(2)Cl(2) with (t)BuONH(2) gave good yields of Ti(NO(t)Bu)Cl(2)(NHMe(2))(2) (1). Compound 1 serves as an excellent entry point into new tert-butoxyimido complexes by reaction with a variety of fac-N(3) donor ligands, namely, Me(3)[9]aneN(3) (tri...

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Publication status:
Published

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Publisher copy:
10.1021/ic201896q

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Journal:
Inorganic chemistry
Volume:
50
Issue:
23
Pages:
12155-12171
Publication date:
2011-12-05
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
URN:
uuid:0e9109ec-7521-4634-9e1d-7398b524b6ca
Source identifiers:
198762
Local pid:
pubs:198762
Language:
English

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