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Cationic terminal borylene complexes: Interconversion of amino and alkoxy borylenes by an unprecedented Meerwein-Ponndorf hydride transfer.

Abstract:
(Chemical Equation Presented) It's all new to B: In the reaction of borylene complex 1 with benzophenone, a Meerwein-Ponndorf β-hydride transfer from the aminoborylene ligand to the coordinated ketone generates 2 (see structure), the first example of an imine-donor-stabilized borylene complex, and the first cationic alkoxyborylene system. © 2006 Wiley-VCH Verlag GmbH and Co. KGaA.
Publication status:
Published

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Publisher copy:
10.1002/anie.200600714

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Harrington, RW More by this author
Journal:
Angewandte Chemie (International ed. in English)
Volume:
45
Issue:
21
Pages:
3513-3516
Publication date:
2006-05-05
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
URN:
uuid:0e7f735c-1933-412a-9b02-48b9f8c683a1
Source identifiers:
46040
Local pid:
pubs:46040
Language:
English
Keywords:

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