Journal article
Cationic terminal borylene complexes: Interconversion of amino and alkoxy borylenes by an unprecedented Meerwein-Ponndorf hydride transfer.
- Abstract:
- (Chemical Equation Presented) It's all new to B: In the reaction of borylene complex 1 with benzophenone, a Meerwein-Ponndorf β-hydride transfer from the aminoborylene ligand to the coordinated ketone generates 2 (see structure), the first example of an imine-donor-stabilized borylene complex, and the first cationic alkoxyborylene system. © 2006 Wiley-VCH Verlag GmbH and Co. KGaA.
- Publication status:
- Published
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- Publisher copy:
- 10.1002/anie.200600714
Authors
- Journal:
- Angewandte Chemie (International ed. in English) More from this journal
- Volume:
- 45
- Issue:
- 21
- Pages:
- 3513-3516
- Publication date:
- 2006-05-01
- DOI:
- EISSN:
-
1521-3773
- ISSN:
-
1433-7851
- Language:
-
English
- Keywords:
- Pubs id:
-
pubs:46040
- UUID:
-
uuid:0e7f735c-1933-412a-9b02-48b9f8c683a1
- Local pid:
-
pubs:46040
- Source identifiers:
-
46040
- Deposit date:
-
2012-12-19
- ARK identifier:
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- Copyright date:
- 2006
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