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Cationic terminal borylene complexes: Interconversion of amino and alkoxy borylenes by an unprecedented Meerwein-Ponndorf hydride transfer.

Abstract:
(Chemical Equation Presented) It's all new to B: In the reaction of borylene complex 1 with benzophenone, a Meerwein-Ponndorf β-hydride transfer from the aminoborylene ligand to the coordinated ketone generates 2 (see structure), the first example of an imine-donor-stabilized borylene complex, and the first cationic alkoxyborylene system. © 2006 Wiley-VCH Verlag GmbH and Co. KGaA.
Publication status:
Published

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Publisher copy:
10.1002/anie.200600714

Authors

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author


Journal:
Angewandte Chemie (International ed. in English) More from this journal
Volume:
45
Issue:
21
Pages:
3513-3516
Publication date:
2006-05-01
DOI:
EISSN:
1521-3773
ISSN:
1433-7851


Language:
English
Keywords:
Pubs id:
pubs:46040
UUID:
uuid:0e7f735c-1933-412a-9b02-48b9f8c683a1
Local pid:
pubs:46040
Source identifiers:
46040
Deposit date:
2012-12-19
ARK identifier:

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