Journal article icon

Journal article

Variable coordination modes of hydrotris(3-isopropyl-4-bromopyrazolyl)borate (Tp') in Fe(II), Mn(II), Cr(II), and Cr(III) Complexes: formation of MTp'Cl (M = Fe and Mn), structural isomerism in CrTp'(2), and the observation of Tp' (-) as an uncoordinated anion.

Abstract:

The syntheses of the 4-coordinate Tp'MCl complexes (where M = Fe (1), Mn (2); and Tp' = hydrotris(3-isopropyl-4-bromopyrazolyl)borate) are described. The single-crystal X-ray structures show that the metal centers have distorted tetrahedral coordination. Analogous reaction of CrCl(2)(MeCN)(2) with TlTp' gave Cr(kappa(3)-Tp')(kappa(2)-Tp') (3) as the initial product. The 5-coordinate structure was assigned by single-crystal X-ray crystallography, and it was found that the kappa(3) ligand had i...

Expand abstract
Publication status:
Published

Actions


Access Document


Publisher copy:
10.1021/ic010125k

Authors


More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Journal:
Inorganic chemistry
Volume:
40
Issue:
13
Pages:
3170-3176
Publication date:
2001-06-05
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
URN:
uuid:0e7a12d6-c54f-4378-91c8-5d6ffe4c3b8d
Source identifiers:
51073
Local pid:
pubs:51073
Language:
English

Terms of use


Metrics



If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP