- Abstract:
-
The syntheses of the 4-coordinate Tp'MCl complexes (where M = Fe (1), Mn (2); and Tp' = hydrotris(3-isopropyl-4-bromopyrazolyl)borate) are described. The single-crystal X-ray structures show that the metal centers have distorted tetrahedral coordination. Analogous reaction of CrCl(2)(MeCN)(2) with TlTp' gave Cr(kappa(3)-Tp')(kappa(2)-Tp') (3) as the initial product. The 5-coordinate structure was assigned by single-crystal X-ray crystallography, and it was found that the kappa(3) ligand had i...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1021/ic010125k
-
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- Journal:
- Inorganic chemistry
- Volume:
- 40
- Issue:
- 13
- Pages:
- 3170-3176
- Publication date:
- 2001-06-05
- DOI:
- EISSN:
-
1520-510X
- ISSN:
-
0020-1669
- URN:
-
uuid:0e7a12d6-c54f-4378-91c8-5d6ffe4c3b8d
- Source identifiers:
-
51073
- Local pid:
- pubs:51073
- Language:
- English
- Copyright date:
- 2001
Journal article
Variable coordination modes of hydrotris(3-isopropyl-4-bromopyrazolyl)borate (Tp') in Fe(II), Mn(II), Cr(II), and Cr(III) Complexes: formation of MTp'Cl (M = Fe and Mn), structural isomerism in CrTp'(2), and the observation of Tp' (-) as an uncoordinated anion.
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