- Abstract:
-
Variable temperature X-ray and neutron powder diffraction techniques have been used to identify structural phase transitions in Cu-rich A(3)A'BO(6) phases. A transition from monoclinic to rhombohedral symmetry was observed by X-ray diffraction between 700 and 500 K in Sr(3)Cu(1-x)M(x)IrO(6) (M = Ni, Zn; 0 < or = x < or = 0.5). The temperature of the phase change decreased in a linear manner with Cu-content and was essentially independent of the nature of M. Ca(3.1)Cu(0.9)MnO(6) was show...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1021/ic0487629
-
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- Journal:
- Inorganic chemistry
- Volume:
- 44
- Issue:
- 2
- Pages:
- 197-205
- Publication date:
- 2005-01-05
- DOI:
- EISSN:
-
1520-510X
- ISSN:
-
0020-1669
- URN:
-
uuid:0e63c091-0d21-4e38-9280-860da033f3f6
- Source identifiers:
-
32956
- Local pid:
- pubs:32956
- Language:
- English
- Copyright date:
- 2005
Journal article
Structural chemistry of A3CuBO6 (A = Ca, Sr; B = Mn, Ru, Ir) as a function of temperature.
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