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Fourier transformed large amplitude square-wave voltammetry as an alternative to impedance spectroscopy: Evaluation of resistance, capacitance and electrode kinetic effects via an heuristic approach

Abstract:

A detailed simulation of Fourier transformed large amplitude square-wave voltammetry is presented in the frequency domain for the process Red ⇌ Ox + e-. The simulation takes into account the influence of the electrode kinetics (Butler-Volmer model), uncompensated resistance (R u) and double layer capacitance (Cdl). Of particular significance is the prediction that the even harmonic responses are only detected in the presence of quasi-reversibility or uncompensated resistance, and also are ess...

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Publication status:
Published

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Publisher copy:
10.1002/elan.200403293

Authors


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Institution:
University of Oxford
Department:
Oxford, MPLS, Computer Science
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Mathematical Institute
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Journal:
ELECTROANALYSIS
Volume:
17
Issue:
15-16
Pages:
1450-1462
Publication date:
2005-08-05
DOI:
EISSN:
1521-4109
ISSN:
1040-0397
URN:
uuid:0e12eb83-4bc4-4c24-9bb5-e571d2a71c04
Source identifiers:
131851
Local pid:
pubs:131851

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