Journal article
Fourier transformed large amplitude square-wave voltammetry as an alternative to impedance spectroscopy: Evaluation of resistance, capacitance and electrode kinetic effects via an heuristic approach
- Abstract:
-
A detailed simulation of Fourier transformed large amplitude square-wave voltammetry is presented in the frequency domain for the process Red ⇌ Ox + e-. The simulation takes into account the influence of the electrode kinetics (Butler-Volmer model), uncompensated resistance (R u) and double layer capacitance (Cdl). Of particular significance is the prediction that the even harmonic responses are only detected in the presence of quasi-reversibility or uncompensated resistance, and also are ess...
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- Publication status:
- Published
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- Publisher copy:
- 10.1002/elan.200403293
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Bibliographic Details
- Journal:
- ELECTROANALYSIS
- Volume:
- 17
- Issue:
- 15-16
- Pages:
- 1450-1462
- Publication date:
- 2005-08-01
- DOI:
- EISSN:
-
1521-4109
- ISSN:
-
1040-0397
- Source identifiers:
-
131851
Item Description
- Keywords:
- Pubs id:
-
pubs:131851
- UUID:
-
uuid:0e12eb83-4bc4-4c24-9bb5-e571d2a71c04
- Local pid:
- pubs:131851
- Deposit date:
- 2012-12-19
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- Copyright date:
- 2005
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