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Using high-throughput techniques to identify complexants for (137)Cs, (60)Co and (90)Sr

Abstract:

High-throughput synthetic and screening methods have been used to prepare and evaluate caesium, cobalt and strontium selective sequestering agents derived from aza-crown ethers. Storage phosphor autoradiography was the screening method used to determine potential lead compounds. The most effective complexants for Cs+ have a very high selectivity over potassium ions and will bind picomolar quantities of Cs+ in the presence of mM K+. The binding and selectivity of these compounds with 60Co and ...

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Publication status:
Published

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Publisher copy:
10.1039/b811359a

Authors


Demetriou, AM More by this author
Crouch, DJ More by this author
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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Yeates, SG More by this author
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Journal:
JOURNAL OF MATERIALS CHEMISTRY
Volume:
18
Issue:
44
Pages:
5350-5353
Publication date:
2008
DOI:
EISSN:
1364-5501
ISSN:
0959-9428
URN:
uuid:0dea4dfd-e81a-41ae-b002-78f7ccd22fe2
Source identifiers:
40973
Local pid:
pubs:40973
Language:
English

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