- Abstract:
-
Chemically induced dynamic nuclear polarisation (CIDNP) is explored as a source of nuclear hyperpolarisation in heteronuclear Overhauser effect experiments. A photochemical reaction proceeding through a radical pair intermediate is used to enhance (19)F nuclear magnetisation in 3-fluorotyrosine by more than an order of magnitude with a corresponding increase in the amplitudes of (19)F-(1)H cross-relaxation and cross-correlation effects. The reactions employed are cyclic and leave the sample c...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1016/j.jmr.2004.01.011
-
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- Journal:
- Journal of magnetic resonance (San Diego, Calif. : 1997)
- Volume:
- 168
- Issue:
- 1
- Pages:
- 1-7
- Publication date:
- 2004-05-05
- DOI:
- EISSN:
-
1096-0856
- ISSN:
-
1090-7807
- URN:
-
uuid:0de3231a-c8f3-4232-acf5-25824e9118be
- Source identifiers:
-
32682
- Local pid:
- pubs:32682
- Language:
- English
- Keywords:
- Copyright date:
- 2004
Journal article
Chemically amplified 19F-1H nuclear Overhauser effects.
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