Journal article

NMR assignment of absolute configuration of a P-chiral diphosphine and mechanics of its stereoselective formation

Abstract:: Two-dimensional rotating-frame nuclear Overhauser enhancement (ROESY) NMR spectra are used to determine the absolute configuration of (+)-diphenyl- phosphine-2,3-dimethyl-7-phenyl-7-phosphabicyclo[2.2.1]hept-2-ene. This diphosphine ligand is obtained from the palladium complex-promoted Diels- Alder reaction between diphenylvinylphosphine and 1-phenyl-3,3- dimethylphosphole in the presence of (R)-dimethyl(1-(α-naphthyl)ethylamine as the chiral auxiliary. The origin of the stereoselectivity in this asymmetric reaction is also revealed by solution NMR studies.

Publication status:: Published

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APA Style

Aw, B., Selvaratnam, S., Leung, P., Rees, N., & McFarlane, W. (1996). NMR assignment of absolute configuration of a P-chiral diphosphine and mechanics of its stereoselective formation. TETRAHEDRON-ASYMMETRY, 7(6), 1753–1762.

MLA Style

Aw, B, et al. “NMR Assignment of Absolute Configuration of a P-Chiral Diphosphine and Mechanics of Its Stereoselective Formation.” TETRAHEDRON-ASYMMETRY, vol. 7, no. 6, 1996, pp. 1753–62.

Chicago Style

Aw, B, S Selvaratnam, P Leung, N Rees, and W McFarlane. 1996. “NMR Assignment of Absolute Configuration of a P-Chiral Diphosphine and Mechanics of Its Stereoselective Formation.” TETRAHEDRON-ASYMMETRY 7 (6): 1753–62.
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Publisher copy:: 10.1016/0957-4166(96)00210-8

Authors

+ Aw, B More by this author

Role:: Author

+ Selvaratnam, S More by this author

Role:: Author

+ Leung, P More by this author

Role:: Author

+ Rees, N More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

+ McFarlane, W More by this author

Role:: Author

Journal:: TETRAHEDRON-ASYMMETRY More from this journal
Volume:: 7
Issue:: 6
Pages:: 1753-1762
Publication date:: 1996-06-01
DOI:: 10.1016/0957-4166(96)00210-8
ISSN:: 0957-4166

Language:: English
Pubs id:: pubs:115951
UUID:: uuid:0dcbf8d0-f033-47eb-931c-13e306c3b486
Local pid:: pubs:115951
Source identifiers:: 115951
Deposit date:: 2012-12-19
ARK identifier:: ark:/29072/ora_0dcbf8d0f03347eb931c13e306c3b486

Terms of use

Copyright date:: 1996

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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