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Structural and magnetic properties of Nd18Li8Co4--xFexO3-y and Nd18Li8Co4-xTixO39-y

Abstract:

Nd18Li8Co3FeO39-y, Nd 18Li8CoFe3O39-y and Nd 18Li8Co3TiO39-y have been synthesised and characterised by neutron powder diffraction, magnetometry and Mössbauer spectroscopy. Their cubic structure (Pm3n, a∼11.9 Å) is based on intersecting <1 1 1> chains comprised of alternating octahedral and trigonal-prismatic coordination sites. These chains lie within hexagonal-prismatic cavities formed by a NdO framework. Each compound has an incomplete oxide sublattice (y∼1), with vacancies located a...

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Publication status:
Published

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Publisher copy:
10.1016/j.jssc.2011.07.020

Authors


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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Dutton, SE More by this author
Grandjean, F More by this author
Thammajak, N More by this author
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Journal:
JOURNAL OF SOLID STATE CHEMISTRY
Volume:
184
Issue:
9
Pages:
2580-2587
Publication date:
2011-09-05
DOI:
EISSN:
1095-726X
ISSN:
0022-4596
URN:
uuid:0d7611c9-c81c-462d-bca5-f98c72021e87
Source identifiers:
177334
Local pid:
pubs:177334

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