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The preparation and structures of hydrogen ordered phases of ice.

Abstract:

Two hydrogen ordered phases of ice were prepared by cooling the hydrogen disordered ices V and XII under pressure. Previous attempts to unlock the geometrical frustration in hydrogen-bonded structures have focused on doping with potassium hydroxide and have had success in partially increasing the hydrogen ordering in hexagonal ice I (ice Ih). By doping ices V and XII with hydrochloric acid, we have prepared ice XIII and ice XIV, and we analyzed their structures by powder neutron diffraction. ...

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Publication status:
Published

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Publisher copy:
10.1126/science.1123896

Authors


Salzmann, CG More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Physics, Condensed Matter Physics
Hallbrucker, A More by this author
Finney, JL More by this author
Journal:
Science (New York, N.Y.)
Volume:
311
Issue:
5768
Pages:
1758-1761
Publication date:
2006-03-05
DOI:
EISSN:
1095-9203
ISSN:
0036-8075
URN:
uuid:0d624583-3f4c-4d79-8aff-0c90708dda54
Source identifiers:
66279
Local pid:
pubs:66279
Language:
English

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