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Low energy structural dynamics and constrained libration of Li(NH3)4, the lowest melting point metal.

Abstract:
The lattice and molecular dynamics for the solid phases of the lowest melting-point metal, Li(NH3)4, are determined by incoherent inelastic neutron scattering. Measurements of internal molecular displacements and distortions of the Li(NH3)4 units have been modelled and assigned using density functional theory calculations for the solid and molecular system. Inelastic neutron scattering measurement allow for the first determination of NH3 librational transitions.
Publication status:
Published

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Publisher copy:
10.1039/c4cc03397c

Authors


Ramirez-Cuesta, AJ More by this author
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Publisher:
Royal Society of Chemistry
Journal:
Chemical communications (Cambridge, England)
Volume:
50
Issue:
74
Pages:
10778-10781
Publication date:
2014-09-05
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
URN:
uuid:0d5ae5fd-e3a2-435e-ac70-7e7c95683015
Source identifiers:
483060
Local pid:
pubs:483060
Language:
English

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