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The Measurement of the Gibbs Energy of Transfer Between Oil and Water Using a Nano-Carbon Paste Electrode

Abstract:

The use of nano-carbon paste electrodes for the measurement of Gibbs energies of transfer between oil and aqueous phases is reported. In this method the oil of interest is used as the binder for the nano-carbon paste electrodes and the molecule of interest is dissolved in the organic or aqueous phase. Voltammetry is performed over a period of time and used to monitor the transfer of the molecule between the two phases. The method is illustrated for the transfer of ferrocenemethanol between wa...

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Publication status:
Published

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Publisher copy:
10.1002/elan.201300478

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
Journal:
ELECTROANALYSIS
Volume:
26
Issue:
2
Pages:
351-358
Publication date:
2014-02-05
DOI:
EISSN:
1521-4109
ISSN:
1040-0397
URN:
uuid:0d187dfd-1788-4865-a3ca-9a37bdec375a
Source identifiers:
452528
Local pid:
pubs:452528

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