Journal article

Charge-compensated carbarhodaboranes. Synthesis and molecular structures of 3-L-3,3-(I)(2)-4-SMe2-3,1,2-closo-RhC2B9H10, L = CO or PPh3

Abstract:: Reaction of 3,3- (CO) 2-4-SMe2-3,1,2-closo-RhC2B9H 10 with iodine results in the formation of 3- (CO) -3,3- (I) 2-4-SMe2-3,1,2-closo-RhC2B9H 10, 1. Reaction between 1 and PPh3 results in substitution of the carbonyl group to afford 3-PPh3-3,3- (I) 2-4-SMe2-3,1,2-closo-RhC2B9H 10, 2. Both new compounds have been fully characterised by multinuclear NMR spectroscopy and also by a single crystal X-ray diffraction studies.

Publication status:: Published

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APA Style

Boyd, A., Rosair, G., Tiarks, F., Weller, A., Zahn, S., & Welch, A. (1998). Charge-compensated carbarhodaboranes. Synthesis and molecular structures of 3-L-3,3-(I)(2)-4-SMe2-3,1,2-closo-RhC2B9H10, L = CO or PPh3. POLYHEDRON, 17(16), 2627–2632.

MLA Style

Boyd, A, et al. “Charge-Compensated Carbarhodaboranes. Synthesis and Molecular Structures of 3-L-3,3-(I)(2)-4-SMe2-3,1,2-Closo-RhC2B9H10, L = CO or PPh3.” POLYHEDRON, vol. 17, no. 16, 1998, pp. 2627–32.

Chicago Style

Boyd, A, G Rosair, F Tiarks, A Weller, S Zahn, and A Welch. 1998. “Charge-Compensated Carbarhodaboranes. Synthesis and Molecular Structures of 3-L-3,3-(I)(2)-4-SMe2-3,1,2-Closo-RhC2B9H10, L = CO or PPh3.” POLYHEDRON 17 (16): 2627–32.
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Publisher copy:: 10.1016/S0277-5387(98)00011-4

Authors

+ Boyd, A More by this author

Role:: Author

+ Rosair, G More by this author

Role:: Author

+ Tiarks, F More by this author

Role:: Author

+ Weller, A More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

+ Zahn, S More by this author

Role:: Author

More authors...

Journal:: POLYHEDRON More from this journal
Volume:: 17
Issue:: 16
Pages:: 2627-2632
Publication date:: 1998-01-01
DOI:: 10.1016/S0277-5387(98)00011-4
ISSN:: 0277-5387

Language:: English
Keywords:: rhodium

synthesis

structure

carbaborane
Pubs id:: pubs:51727
UUID:: uuid:0cf8ff6d-9d33-41ce-9ec3-6fa48932482f
Local pid:: pubs:51727
Source identifiers:: 51727
Deposit date:: 2012-12-19
ARK identifier:: ark:/29072/ora_0cf8ff6d9d3341ce9ec36fa48932482f

Terms of use

Copyright date:: 1998

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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