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ORGANOMETALLIC PHOTOELECTROCHEMISTRY - OXIDATION OF FAC-TRICARBONYLCHLORO[BIS(DIPHENYLPHOSPHINO)METHANE]MANGANESE(I)

Abstract:

The electrochemical oxidation of fac-tricarbonylchloro[bis(diphenylphosphino)methane]manganese(I) (FCM) has been studied at an irradiated (390-nm) channel electrode. Photocurrent measurements made as a function of variable mass transport, combined with simultaneous photoelectrochemical ESR measurements, have shown that new electrode reaction pathways appear under illumination. Specifically, first, light can induce a fac to mer isomerization in the molecule which leads to oxidation at potentia...

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Publication status:
Published

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Publisher copy:
10.1021/j100110a031

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Journal:
JOURNAL OF PHYSICAL CHEMISTRY More from this journal
Volume:
97
Issue:
8
Pages:
1661-1664
Publication date:
1993-02-25
DOI:
EISSN:
1541-5740
ISSN:
0022-3654
Language:
English
UUID:
uuid:0cdd30e8-f941-4fbe-a365-26e4ef168d89
Local pid:
pubs:44145
Source identifiers:
44145
Deposit date:
2012-12-19

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