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The theory of electrodeposition in the presence of forced convection: transport controlled nucleation of hemispheres

Abstract:

A new equation to describe the diffusion controlled nucleation of hemispherical centres under conditions of forced convection is derived, in a manner similar to that of the Scharifker and Mostany equation (J. Electroanal. Chem. 177 (1984) 13). It has been shown that the transients measured under these conditions should show a monotonically rising transient, followed by convergence to a limiting current. The accuracy and validity of the model is tested by comparison with experimental data obta...

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Publication status:
Published

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Authors


Klymenko, OV More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Journal:
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume:
534
Issue:
1
Pages:
13-17
Publication date:
2002-10-04
DOI:
ISSN:
0022-0728
URN:
uuid:0cd567b8-2aee-4bf6-87ac-ea6095c03760
Source identifiers:
38412
Local pid:
pubs:38412

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