- Abstract:
-
A new equation to describe the diffusion controlled nucleation of hemispherical centres under conditions of forced convection is derived, in a manner similar to that of the Scharifker and Mostany equation (J. Electroanal. Chem. 177 (1984) 13). It has been shown that the transients measured under these conditions should show a monotonically rising transient, followed by convergence to a limiting current. The accuracy and validity of the model is tested by comparison with experimental data obta...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1016/S0022-0728(02)01103-8
-
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- Journal:
- JOURNAL OF ELECTROANALYTICAL CHEMISTRY
- Volume:
- 534
- Issue:
- 1
- Pages:
- 13-17
- Publication date:
- 2002-10-04
- DOI:
- ISSN:
-
0022-0728
- URN:
-
uuid:0cd567b8-2aee-4bf6-87ac-ea6095c03760
- Source identifiers:
-
38412
- Local pid:
- pubs:38412
- Language:
- English
- Keywords:
- Copyright date:
- 2002
Journal article
The theory of electrodeposition in the presence of forced convection: transport controlled nucleation of hemispheres
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