Journal article
VOLTAMMETRIC AND NMR-STUDIES OF A BIS(FERROCENECARBOXAMIDE)-SUBSTITUTED DIAZA 18-CROWN-6 RECEPTOR THAT SIMULTANEOUSLY COMPLEXES AND ELECTROCHEMICALLY RECOGNIZES BOTH CATIONS AND ANIONS
- Abstract:
- Voltammetric and NMR investigations of a bis(ferrocenecarboxamide)-substituted diaza 18-crown-6 receptor in an aprotic environment have been carried out. This receptor molecule can complex metal cations or anions individually and can accommodate both a cation and anion. The binding of anions is significantly enhanced by the presence of a bound metal cation, with selectivity for HSO4- over Cl-. The receptor is capable of electrochemically recognising the complexed anions, cations and anion/cation pairs.
- Publication status:
- Published
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- Publisher copy:
- 10.1039/ft9959100295
Authors
- Journal:
- JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS More from this journal
- Volume:
- 91
- Issue:
- 2
- Pages:
- 295-302
- Publication date:
- 1995-01-21
- DOI:
- EISSN:
-
1364-5455
- ISSN:
-
0956-5000
- Language:
-
English
- Pubs id:
-
pubs:44738
- UUID:
-
uuid:0cd52ae8-a0ba-4073-82ce-a2b5af25ccb4
- Local pid:
-
pubs:44738
- Source identifiers:
-
44738
- Deposit date:
-
2012-12-19
- ARK identifier:
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- Copyright date:
- 1995
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