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VOLTAMMETRIC AND NMR-STUDIES OF A BIS(FERROCENECARBOXAMIDE)-SUBSTITUTED DIAZA 18-CROWN-6 RECEPTOR THAT SIMULTANEOUSLY COMPLEXES AND ELECTROCHEMICALLY RECOGNIZES BOTH CATIONS AND ANIONS

Abstract:
Voltammetric and NMR investigations of a bis(ferrocenecarboxamide)-substituted diaza 18-crown-6 receptor in an aprotic environment have been carried out. This receptor molecule can complex metal cations or anions individually and can accommodate both a cation and anion. The binding of anions is significantly enhanced by the presence of a bound metal cation, with selectivity for HSO4- over Cl-. The receptor is capable of electrochemically recognising the complexed anions, cations and anion/cation pairs.
Publication status:
Published

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Publisher copy:
10.1039/ft9959100295

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Journal:
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS
Volume:
91
Issue:
2
Pages:
295-302
Publication date:
1995-01-21
DOI:
EISSN:
1364-5455
ISSN:
0956-5000
URN:
uuid:0cd52ae8-a0ba-4073-82ce-a2b5af25ccb4
Source identifiers:
44738
Local pid:
pubs:44738
Language:
English

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