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Time resolved FTIR emission measurements of the internal energies of NO formed in the O(D-1)+N2O reaction, and energy transfer processes to N2O

Abstract:

Time resolved infrared emission from the fundamental and first overtone transitions of NO(v = 1-14), produced in the reaction of N2O with O(1D) has been analysed to determine the nascent vibrational distribution of NO. The electronically excited O atom was produced by the 193 nm laser photolysis of N2O. The measured vibrational distribution was found to be monotonically decreasing as a function of increasing v. Lower limits were determined for the average nascent rotational energy in v = 1-6,...

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Publication status:
Published

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Publisher copy:
10.1039/b300163f

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
Journal:
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume:
5
Issue:
11
Pages:
2369-2375
Publication date:
2003-01-01
DOI:
EISSN:
1463-9084
ISSN:
1463-9076
URN:
uuid:0cd3b710-927e-45dd-b0e7-64fa979bddb4
Source identifiers:
38660
Local pid:
pubs:38660
Language:
English

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