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Morphology-dependent interactions of ZnO with Cu nanoparticles at the materials' interface in selective hydrogenation of CO2 to CH3OH.

Abstract:
A good face: The (002) polar facet of platelike ZnO nanoparticles gives a much stronger electronic interaction with Cu nanoparticles than other facets (see picture; CB=conductance band; VB=valence band) and shows higher selectivity in the catalytic hydrogenation of CO2 to methanol. This finding provides the basis for the rational design of new nanocatalysts for CO 2 hydrogenation. © 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim.
Publication status:
Published

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Publisher copy:
10.1002/anie.201007108

Authors


Tedsree, K More by this author
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Journal:
Angewandte Chemie (International ed. in English)
Volume:
50
Issue:
9
Pages:
2162-2165
Publication date:
2011-02-05
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
URN:
uuid:0cab80e2-c568-42ee-9ee2-69e60381e992
Source identifiers:
180311
Local pid:
pubs:180311

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