Journal article icon

Journal article

An unexpected pathway for the catalytic oxidation of methylidyne on Rh{111} as a route to syngas.

Abstract:

This study investigates the adsorption properties of methylidyne (CH) on Rh{111}, its partial and full oxidation as well as its surface mobility, by means of plane-wave density functional theory (DFT) calculations. Besides investigating known oxidation pathways on rhodium, such as decomposition of CH and subsequent oxidation of the decomposition products, new pathways such as direct reaction of methylidyne and oxygen toward a surface aldyhyde-type species and the decomposition of this species...

Expand abstract

Actions


Access Document


Publisher copy:
10.1021/ja067722w

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Role:
Author
Journal:
Journal of the American Chemical Society
Volume:
129
Issue:
6
Pages:
1751-1759
Publication date:
2007-02-01
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
Source identifiers:
265362
Language:
English
Pubs id:
pubs:265362
UUID:
uuid:0c8d48d5-4a9d-4e48-be2d-cee04fd53fc2
Local pid:
pubs:265362
Deposit date:
2013-11-17

Terms of use


Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP