Journal article
3,4-O-isopropylidene-2-C-methl-D-arabinono-1,5-lactone
- Abstract:
- The crystal structure of δ-lactone, C9H14O 5, formed in high diastereoselectivity by the Kiliani reaction of a protected 1-deoxyketose was described. It was observed that the δ-lactone compound adopts a boat conformation in which an OH group occupies a flagpole position. The hydroxy group at atom C1 was clearly found to be in a very hindered position, being additionally attached to a tertiary C atom. As usually expected for sugar derivatives, hydrogen bonding was found to occur between molecules.
- Publication status:
- Published
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- Publisher copy:
- 10.1107/S1600536804032659
Authors
- Journal:
- ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE More from this journal
- Volume:
- 61
- Issue:
- 1
- Pages:
- O127-O129
- Publication date:
- 2005-01-01
- DOI:
- EISSN:
-
1600-5368
- ISSN:
-
1600-5368
- Language:
-
English
- Pubs id:
-
pubs:39372
- UUID:
-
uuid:0c76ffb9-fa83-47e9-8702-cb7e824f19d4
- Local pid:
-
pubs:39372
- Source identifiers:
-
39372
- Deposit date:
-
2012-12-19
- ARK identifier:
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- Copyright date:
- 2005
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