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Journal article

3,4-O-isopropylidene-2-C-methl-D-arabinono-1,5-lactone

Abstract:
The crystal structure of δ-lactone, C9H14O 5, formed in high diastereoselectivity by the Kiliani reaction of a protected 1-deoxyketose was described. It was observed that the δ-lactone compound adopts a boat conformation in which an OH group occupies a flagpole position. The hydroxy group at atom C1 was clearly found to be in a very hindered position, being additionally attached to a tertiary C atom. As usually expected for sugar derivatives, hydrogen bonding was found to occur between molecules.
Publication status:
Published

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Publisher copy:
10.1107/S1600536804032659

Authors

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author


Journal:
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE More from this journal
Volume:
61
Issue:
1
Pages:
O127-O129
Publication date:
2005-01-01
DOI:
EISSN:
1600-5368
ISSN:
1600-5368


Language:
English
Pubs id:
pubs:39372
UUID:
uuid:0c76ffb9-fa83-47e9-8702-cb7e824f19d4
Local pid:
pubs:39372
Source identifiers:
39372
Deposit date:
2012-12-19
ARK identifier:

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