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Thermodynamics of binding of carboxylates to amphiphilic Eu(3+)/Cu(2+) metallacrown.

Abstract:
The binding constants of acetate and benzoate to a Pheha-based 15-metallacrown-5 have been determined by a fluorimetric indicator displacement assay demonstrating on a thermodynamic basis the stabilization effect arising from complexation of the less polar carboxylate into the hydrophobic pocket of the metallacrown scaffold.
Publication status:
Published

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Publisher copy:
10.1039/b911512a

Authors

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author


Journal:
Dalton transactions (Cambridge, England : 2003) More from this journal
Issue:
34
Pages:
6705-6708
Publication date:
2009-09-01
DOI:
EISSN:
1477-9234
ISSN:
1477-9226


Language:
English
Pubs id:
pubs:399447
UUID:
uuid:0c635b61-c953-4c66-87d1-b151a47ea83e
Local pid:
pubs:399447
Source identifiers:
399447
Deposit date:
2013-11-16
ARK identifier:

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