Journal article
Thermodynamics of binding of carboxylates to amphiphilic Eu(3+)/Cu(2+) metallacrown.
- Abstract:
- The binding constants of acetate and benzoate to a Pheha-based 15-metallacrown-5 have been determined by a fluorimetric indicator displacement assay demonstrating on a thermodynamic basis the stabilization effect arising from complexation of the less polar carboxylate into the hydrophobic pocket of the metallacrown scaffold.
- Publication status:
- Published
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- Publisher copy:
- 10.1039/b911512a
Authors
- Journal:
- Dalton transactions (Cambridge, England : 2003) More from this journal
- Issue:
- 34
- Pages:
- 6705-6708
- Publication date:
- 2009-09-01
- DOI:
- EISSN:
-
1477-9234
- ISSN:
-
1477-9226
- Language:
-
English
- Pubs id:
-
pubs:399447
- UUID:
-
uuid:0c635b61-c953-4c66-87d1-b151a47ea83e
- Local pid:
-
pubs:399447
- Source identifiers:
-
399447
- Deposit date:
-
2013-11-16
- ARK identifier:
Terms of use
- Copyright date:
- 2009
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