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Reactions at solid-liquid interfaces. The mechanism and kinetics of the fluorination of 2,4-dinitrochlorobenzene using solid potassium fluoride in dimethylformamide

Abstract:

The halogen exchange reaction of 2,4-dichloronitrobenzene with potassium fluoride in dimethylformamide containing tetrabutylammonium salts has been studied employing an electrochemical detection methodology based upon the use of square wave voltammetry to follow the loss of reactant and the formation of the product and intermediates. The results obtained show that the kinetics of loss of parent material behave on one hand as a dissolution-rate-controlled process and on the other as a homogene...

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Publication status:
Published

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Publisher copy:
10.1021/jp012612r

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
JOURNAL OF PHYSICAL CHEMISTRY B More from this journal
Volume:
105
Issue:
50
Pages:
12534-12546
Publication date:
2001-12-20
DOI:
EISSN:
1520-5207
ISSN:
1520-6106
Language:
English
UUID:
uuid:0c3fb565-4900-4326-b72a-a86ef297ef80
Local pid:
pubs:38133
Source identifiers:
38133
Deposit date:
2012-12-19

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