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Reactions at solid-liquid interfaces. The mechanism and kinetics of the fluorination of 2,4-dinitrochlorobenzene using solid potassium fluoride in dimethylformamide

Abstract:: The halogen exchange reaction of 2,4-dichloronitrobenzene with potassium fluoride in dimethylformamide containing tetrabutylammonium salts has been studied employing an electrochemical detection methodology based upon the use of square wave voltammetry to follow the loss of reactant and the formation of the product and intermediates. The results obtained show that the kinetics of loss of parent material behave on one hand as a dissolution-rate-controlled process and on the other as a homogene...
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Publication status:: Published

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APA Style

Macfie, G., Brookes, B., & Compton, R. (2001). Reactions at solid-liquid interfaces. The mechanism and kinetics of the fluorination of 2,4-dinitrochlorobenzene using solid potassium fluoride in dimethylformamide. JOURNAL OF PHYSICAL CHEMISTRY B, 105(50), 12534–12546.

MLA Style

Macfie, G., et al. “Reactions at Solid-Liquid Interfaces. The Mechanism and Kinetics of the Fluorination of 2,4-Dinitrochlorobenzene Using Solid Potassium Fluoride in Dimethylformamide.” JOURNAL OF PHYSICAL CHEMISTRY B, vol. 105, no. 50, 2001, pp. 12534–46.

Chicago Style

Macfie, G, B Brookes, and R Compton. 2001. “Reactions at Solid-Liquid Interfaces. The Mechanism and Kinetics of the Fluorination of 2,4-Dinitrochlorobenzene Using Solid Potassium Fluoride in Dimethylformamide.” JOURNAL OF PHYSICAL CHEMISTRY B 105 (50): 12534–46.
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Publisher copy:: 10.1021/jp012612r

Authors

+ Macfie, G More by this author

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Author

+ Brookes, B More by this author

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Author

+ Compton, R More by this author

Institution:

University of Oxford

Division:

MPLS

Department:

Chemistry

Sub department:

Physical & Theoretical Chem

Role:

Author

Bibliographic Details

Journal:: JOURNAL OF PHYSICAL CHEMISTRY B
Volume:: 105
Issue:: 50
Pages:: 12534-12546
Publication date:: 2001-12-20
DOI:: 10.1021/jp012612r
EISSN:: 1520-5207
ISSN:: 1520-6106

Item Description

Language:: English
UUID:: uuid:0c3fb565-4900-4326-b72a-a86ef297ef80
Local pid:: pubs:38133
Source identifiers:: 38133
Deposit date:: 2012-12-19

Terms of use

Copyright date:: 2001

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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