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Oxygen reduction catalysis at anthraquinone centres molecularly wired via carbon nanotubes

Abstract:
Multi-walled carbon nanotubes (MWCNTs) have been chemically derivatised via the reduction of anthraquinone-1-diazonium chloride with hypophosphorous acid to attach 1-anthraquinonyl groups to the MWCNTs, most likely at edge plane like defects. The covalently attached quinone moiety attached to the nanotubes (‘molecular wire’) acts as an effective mediator for the electrocatalytic reduction of oxygen.
Publication status:
Published

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Publisher copy:
10.1007/BF03245781

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
Journal:
Journal of the Iranian Chemical Society
Volume:
2
Issue:
1
Pages:
60-64
Publication date:
2005-03-05
DOI:
ISSN:
1735-207X
URN:
uuid:0c312141-1b50-4864-9ba3-d701062029c2
Source identifiers:
40025
Local pid:
pubs:40025

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