Journal article

Stereospecific anti SE2' fluorination of allenylsilanes: synthesis of enantioenriched propargylic fluorides.

Abstract:: The electrophilic fluorodesilylation of enantioenriched allenylsilanes proceeds with efficient transfer of chirality. The silylation-fluorination of propargylic alcohols occurs with overall retention of stereochemistry, a result consistent with a stereospecific anti S(E)2' mechanism for the fluorination step.

Publication status:: Published

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APA Style

Carroll, L., McCullough, S., Rees, T., Claridge, T., & Gouverneur, V. (2008). Stereospecific anti SE2' fluorination of allenylsilanes: synthesis of enantioenriched propargylic fluorides. Organic and Biomolecular Chemistry, 6(10), 1731–1733.

MLA Style

Carroll, L, et al. “Stereospecific Anti SE2' Fluorination of Allenylsilanes: Synthesis of Enantioenriched Propargylic Fluorides.” Organic and Biomolecular Chemistry, vol. 6, no. 10, 2008, pp. 1731–33.

Chicago Style

Carroll, L, S McCullough, T Rees, T Claridge, and V Gouverneur. 2008. “Stereospecific Anti SE2' Fluorination of Allenylsilanes: Synthesis of Enantioenriched Propargylic Fluorides.” Organic and Biomolecular Chemistry 6 (10): 1731–33.
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Publisher copy:: 10.1039/b803888k

Authors

+ Carroll, L More by this author

Role:: Author

+ McCullough, S More by this author

Role:: Author

+ Rees, T More by this author

Role:: Author

+ Claridge, T More by this author

Role:: Author

+ Gouverneur, V More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Organic Chemistry
Role:: Author

Journal:: Organic and biomolecular chemistry More from this journal
Volume:: 6
Issue:: 10
Pages:: 1731-1733
Publication date:: 2008-05-01
DOI:: 10.1039/b803888k
EISSN:: 1477-0539
ISSN:: 1477-0520

Language:: English
Pubs id:: pubs:34225
UUID:: uuid:0c2f744b-68bc-4055-bbae-c333efd95614
Local pid:: pubs:34225
Source identifiers:: 34225
Deposit date:: 2012-12-19
ARK identifier:: ark:/29072/ora_0c2f744b68bc4055bbaec333efd95614

Terms of use

Copyright date:: 2008

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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