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Isolation and spectroscopic characterization of two isomers of the metallofullerene Nd@C82

Abstract:

For the first time, two types of the metallofullerene Nd@C82 have been isolated and characterized. HPLC was used to isolate Nd@C 82(I, II). The two isomers were characterized by mass spectrometry and UV-Vis-NIR absorption spectroscopy. Nd@C82(I) was found to be similar in structure to the main isomer of other lanthanofullerenes such as La@C82, as was previously reported. We assign Nd@C82(I) to have a C2v cage symmetry. Nd@C82(II) showed a markedly different UV-Vis-NIR absorption spectrum to N...

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Publisher copy:
10.1063/1.2103824

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Institution:
University of Oxford
Division:
MPLS
Department:
Physics
Sub department:
Condensed Matter Physics
Role:
Author
Journal:
AIP Conference Proceedings More from this journal
Volume:
786
Pages:
73-76
Publication date:
2005-09-27
DOI:
EISSN:
1551-7616
ISSN:
0094-243X
Language:
English
Pubs id:
pubs:178465
UUID:
uuid:0c13a088-afb8-4110-8eab-07de53548f3f
Local pid:
pubs:178465
Source identifiers:
178465
Deposit date:
2013-02-20

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