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Isolation and spectroscopic characterization of two isomers of the metallofullerene Nd@C82

Abstract:: For the first time, two types of the metallofullerene Nd@C82 have been isolated and characterized. HPLC was used to isolate Nd@C 82(I, II). The two isomers were characterized by mass spectrometry and UV-Vis-NIR absorption spectroscopy. Nd@C82(I) was found to be similar in structure to the main isomer of other lanthanofullerenes such as La@C82, as was previously reported. We assign Nd@C82(I) to have a C2v cage symmetry. Nd@C82(II) showed a markedly different UV-Vis-NIR absorption spectrum to N...
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APA Style

Porfyrakis, K., Kanai, M., Morley, G., Ardavan, A., Dennis, T., & Briggs, G. (2005). Isolation and spectroscopic characterization of two isomers of the metallofullerene Nd@C82 . AIP Conference Proceedings, 786, 73–76.

MLA Style

Porfyrakis, K., et al. “Isolation and Spectroscopic Characterization of Two Isomers of the Metallofullerene Nd@C82 .” AIP Conference Proceedings, vol. 786, 2005, pp. 73–76.

Chicago Style

Porfyrakis, K, M Kanai, G Morley, A Ardavan, T Dennis, and G Briggs. 2005. “Isolation and Spectroscopic Characterization of Two Isomers of the Metallofullerene Nd@C82 .” AIP Conference Proceedings 786: 73–76.
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Publisher copy:: 10.1063/1.2103824

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+ Porfyrakis, K More by this author

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+ Kanai, M More by this author

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+ Morley, G More by this author

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+ Ardavan, A More by this author

Institution:

University of Oxford

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MPLS

Department:

Physics

Sub department:

Condensed Matter Physics

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+ Dennis, T More by this author

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Bibliographic Details

Journal:: AIP Conference Proceedings
Volume:: 786
Pages:: 73-76
Publication date:: 2005-09-27
DOI:: 10.1063/1.2103824
EISSN:: 1551-7616
ISSN:: 0094-243X

Item Description

Language:: English
Pubs id:: pubs:178465
UUID:: uuid:0c13a088-afb8-4110-8eab-07de53548f3f
Local pid:: pubs:178465
Source identifiers:: 178465
Deposit date:: 2013-02-20

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Copyright date:: 2005

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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