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Reversible size control of silver nanoclusters via ligand-exchange

Abstract:

The properties of atomically monodisperse noble metal nanoclusters (NCs) are intricately intertwined with their precise molecular formula. The vast majority of size-specific NC syntheses start from the reduction of the metal salt and thiol ligand mixture. Only in gold was it recently shown that ligand-exchange could induce the growth of NCs from one atomically precise species to another, a process of yet unknown reversibility. Here, we present a process for the ligand-exchange-induced growth ...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted Manuscript

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Publisher copy:
10.1021/acs.chemmater.5b00650

Authors


Bootharaju, MS More by this author
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Department:
Oxford, MPLS, Mathematical Institute, Materials
Besong, TMD More by this author
AbdulHalim, LG More by this author
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Publisher:
American Chemical Society Publisher's website
Journal:
Chemistry of Materials Journal website
Volume:
27
Issue:
12
Pages:
4289-4297
Publication date:
2015-05-21
DOI:
EISSN:
1520-5002
ISSN:
0897-4756
Pubs id:
pubs:533302
URN:
uri:0c0d12ec-940e-481d-8780-2e50eeffaf7a
UUID:
uuid:0c0d12ec-940e-481d-8780-2e50eeffaf7a
Local pid:
pubs:533302
Keywords:

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