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The effect of reagent translational energy on the dynamics of the reaction O(P-3)+CS(X(1)Sigma(+))->CO(X(1)Sigma(+))+S(P-3)

Abstract:

Two different regimes of collision energy are used tp explore the role of additional translational energy on the dynamics of the reaction O(3P)+CS(X 1Σ+)→CO(X 1Σ+)+S(3P). Product CO rotational quantum-state population distributions for CO(υ′=12, 13, and 14) are used as an indicator of the reaction dynamics, and these rotational distributions are presented for reaction of thermal reagents (at 298 K) and for translationally hot oxygen atoms formed by the 355 nm photolysis of NO2. The experiment...

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Publication status:
Published

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Publisher copy:
10.1063/1.474097

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
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Journal:
JOURNAL OF CHEMICAL PHYSICS
Volume:
106
Issue:
4
Pages:
1391-1401
Publication date:
1997-01-22
DOI:
ISSN:
0021-9606
URN:
uuid:0bfddbeb-8f49-44ba-8d52-6a0cf3d004de
Source identifiers:
45482
Local pid:
pubs:45482

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