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The effect of reagent translational energy on the dynamics of the reaction O(P-3)+CS(X(1)Sigma(+))->CO(X(1)Sigma(+))+S(P-3)

Abstract:

Two different regimes of collision energy are used tp explore the role of additional translational energy on the dynamics of the reaction O(3P)+CS(X 1Σ+)→CO(X 1Σ+)+S(3P). Product CO rotational quantum-state population distributions for CO(υ′=12, 13, and 14) are used as an indicator of the reaction dynamics, and these rotational distributions are presented for reaction of thermal reagents (at 298 K) and for translationally hot oxygen atoms formed by the 355 nm photolysis of NO2. The experiment...

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Publication status:
Published

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Publisher copy:
10.1063/1.474097

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
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Journal:
JOURNAL OF CHEMICAL PHYSICS
Volume:
106
Issue:
4
Pages:
1391-1401
Publication date:
1997-01-22
DOI:
ISSN:
0021-9606
Source identifiers:
45482
Pubs id:
pubs:45482
UUID:
uuid:0bfddbeb-8f49-44ba-8d52-6a0cf3d004de
Local pid:
pubs:45482
Deposit date:
2012-12-19

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