Journal article
A tetracoordinated rhodium aminyl radical complex.
- Abstract:
- A [16 + 1] valence electron configured rhodium aminyl radical complex could be synthesized and characterized in detail by pulse EPR spectroscopy and DFT calculations. The unpaired electron is delocalized over the metal center and two adjacent nitrogens. H-abstraction reactions from thiols and triethylsilane show that the spin density is predominantly localized on both nitrogens.
- Publication status:
- Published
Actions
Authors
Bibliographic Details
- Journal:
- Journal of the American Chemical Society
- Volume:
- 128
- Issue:
- 20
- Pages:
- 6578-6580
- Publication date:
- 2006-05-01
- DOI:
- EISSN:
-
1520-5126
- ISSN:
-
0002-7863
- Source identifiers:
-
326061
Item Description
- Language:
- English
- Keywords:
- Pubs id:
-
pubs:326061
- UUID:
-
uuid:0bdd5e33-007a-4ff3-a39e-89019189a3cb
- Local pid:
- pubs:326061
- Deposit date:
- 2012-12-19
Terms of use
- Copyright date:
- 2006
If you are the owner of this record, you can report an update to it here: Report update to this record