Journal article

A tetracoordinated rhodium aminyl radical complex.

Abstract:: A [16 + 1] valence electron configured rhodium aminyl radical complex could be synthesized and characterized in detail by pulse EPR spectroscopy and DFT calculations. The unpaired electron is delocalized over the metal center and two adjacent nitrogens. H-abstraction reactions from thiols and triethylsilane show that the spin density is predominantly localized on both nitrogens.

Publication status:: Published

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APA Style

Maire, P., Königsmann, M., Sreekanth, A., Harmer, J., Schweiger, A., & Grützmacher, H. (2006). A tetracoordinated rhodium aminyl radical complex. Journal of the American Chemical Society, 128(20), 6578–6580.

MLA Style

Maire, P, et al. “A Tetracoordinated Rhodium Aminyl Radical Complex.” Journal of the American Chemical Society, vol. 128, no. 20, 2006, pp. 6578–80.

Chicago Style

Maire, P, M Königsmann, A Sreekanth, J Harmer, A Schweiger, and H Grützmacher. 2006. “A Tetracoordinated Rhodium Aminyl Radical Complex.” Journal of the American Chemical Society 128 (20): 6578–80.
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Publisher copy:: 10.1021/ja0612798

Authors

+ Maire, P More by this author

Role:: Author

+ Königsmann, M More by this author

Role:: Author

+ Sreekanth, A More by this author

Role:: Author

+ Harmer, J More by this author

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+ Schweiger, A More by this author

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Journal:: Journal of the American Chemical Society More from this journal
Volume:: 128
Issue:: 20
Pages:: 6578-6580
Publication date:: 2006-05-01
DOI:: 10.1021/ja0612798
EISSN:: 1520-5126
ISSN:: 0002-7863

Language:: English
Keywords:: Organometallic Compounds

Models, Molecular

Rhodium

Electron Spin Resonance Spectroscopy

Tropanes
Pubs id:: pubs:326061
UUID:: uuid:0bdd5e33-007a-4ff3-a39e-89019189a3cb
Local pid:: pubs:326061
Source identifiers:: 326061
Deposit date:: 2012-12-19
ARK identifier:: ark:/29072/ora_0bdd5e33007a4ff3a39e89019189a3cb

Terms of use

Copyright date:: 2006

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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