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A tetracoordinated rhodium aminyl radical complex.

Abstract:
A [16 + 1] valence electron configured rhodium aminyl radical complex could be synthesized and characterized in detail by pulse EPR spectroscopy and DFT calculations. The unpaired electron is delocalized over the metal center and two adjacent nitrogens. H-abstraction reactions from thiols and triethylsilane show that the spin density is predominantly localized on both nitrogens.
Publication status:
Published

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Publisher copy:
10.1021/ja0612798

Authors


Königsmann, M More by this author
Sreekanth, A More by this author
Schweiger, A More by this author
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Journal:
Journal of the American Chemical Society
Volume:
128
Issue:
20
Pages:
6578-6580
Publication date:
2006-05-05
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
URN:
uuid:0bdd5e33-007a-4ff3-a39e-89019189a3cb
Source identifiers:
326061
Local pid:
pubs:326061

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