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Beyond surface redox and oxygen mobility at pd-polar ceria (100) interface: Underlying principle for strong metal-support interactions in green catalysis

Abstract:

When ceria is used as a support for many redox catalysis involved in green catalysis, it is well-known that the overlying noble metal can gain access to a significant quantity of oxygen atoms with high mobility and fast reduction and oxidation properties under mild conditions. However, it is as yet unclear what the underlying principle and the nature of the ceria surface involved are. By using two tailored morphologies of ceria nanocrystals, namely cubes and rods, it is demonstrated from Scan...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1016/j.apcatb.2020.118843

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Role:
Author
Publisher:
Elsevier Publisher's website
Journal:
Applied Catalysis B: Environmental Journal website
Volume:
270
Article number:
118843
Publication date:
2020-03-04
Acceptance date:
2020-02-29
DOI:
EISSN:
1873-3883
ISSN:
0926-3373
Language:
English
Keywords:
Pubs id:
1097188
Local pid:
pubs:1097188
Deposit date:
2020-07-31

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