Journal article

Calix[4] semitube diquinone: a potassium selective redox-active ionophore

Abstract:: Oxidation of calix[4]semitube with Tl(OCOCF 3) 3 in TFA (trifluoroacetic acid) affords the novel redox-active ionophore calix[4]semitube diquinone. This receptor displays a remarkable selectivity preference for potassium cations over all other Group 1 metal cations, a property mirroring that of the parent calix[4]semitube, however its kinetics of complexation are relatively slow. The receptor exhibits substantial electrochemical recognition effets towards sodium and potassium cations.

Publication status:: Published

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APA Style

Webber, P., Cowley, A., & Beer, P. (2003). Calix[4] semitube diquinone: a potassium selective redox-active ionophore. DALTON TRANSACTIONS, 20, 3922–3926.

MLA Style

Webber, P, et al. “Calix[4] Semitube Diquinone: a Potassium Selective Redox-Active Ionophore.” DALTON TRANSACTIONS, no. 20, 2003, pp. 3922–26.

Chicago Style

Webber, P, A Cowley, and P Beer. 2003. “Calix[4] Semitube Diquinone: a Potassium Selective Redox-Active Ionophore.” DALTON TRANSACTIONS, no. 20: 3922–26.
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Publisher copy:: 10.1039/b307419f

Authors

+ Webber, P More by this author

Role:: Author

+ Cowley, A More by this author

Role:: Author

+ Beer, P More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

Journal:: DALTON TRANSACTIONS More from this journal
Issue:: 20
Pages:: 3922-3926
Publication date:: 2003-01-01
DOI:: 10.1039/b307419f
EISSN:: 1477-9234
ISSN:: 1477-9226

Language:: English
Pubs id:: pubs:38839
UUID:: uuid:0b8463f3-59f2-4acb-9fe5-7053ab12886e
Local pid:: pubs:38839
Source identifiers:: 38839
Deposit date:: 2012-12-19
ARK identifier:: ark:/29072/ora_0b8463f359f24acb9fe57053ab12886e

Terms of use

Copyright date:: 2003

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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