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Heteroatomic molecular clusters derived from Group 15 Zintl ion cages: synthesis and isolation of [M2(HP7)2](2-) (M=Ag, Au), two novel cluster anions exhibiting metallophilic interactions.

Abstract:

Ethylenediamine (en) solutions of K(3)P(7) and 2,2,2-crypt (4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo[8.8.8]hexacosane) were reacted with the homoleptic group 11 complexes [M(nbe)(3)][SbF(6)] (M = Ag, Au; nbe = norbornene) yielding two novel cluster anions, [M(2)(HP(7))(2)](2-), both of which were isolated in low crystalline yields as [K(2,2,2-crypt)](2)[M(2)(HP(7))(2)] (M = Ag (1) and Au (2)). Optimization of the reaction conditions by incorporation of a proton source (ammonium tetraphenylbo...

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Publication status:
Published

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Publisher copy:
10.1021/ic102516g

Authors


More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Journal:
Inorganic chemistry
Volume:
50
Issue:
9
Pages:
4021-4028
Publication date:
2011-05-05
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
URN:
uuid:0b835184-4957-447a-9bd2-22573f642be0
Source identifiers:
127175
Local pid:
pubs:127175
Language:
English

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