- Abstract:
-
New acyclic tripodal mono- and 1,1′-bis-substituted amide-linked cobaltocenium ligands have been prepared. Proton NMR spectroscopic and cyclic voltammetric anion co-ordination investigations reveal that the combination of a positively charged cobaltocenium unit together with an amide N-H group are the essential components for the molecular and electrochemical recognition of anionic guest species. Correlations were found to exist between Hammett σ p values of electron-donating and -withdrawing...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1039/dt9930001327
-
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- Journal:
- JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
- Issue:
- 8
- Pages:
- 1327-1332
- Publication date:
- 1993-04-07
- DOI:
- EISSN:
-
1364-5447
- ISSN:
-
0300-9246
- URN:
-
uuid:0b82c8fa-a801-4104-b814-73f724f25981
- Source identifiers:
-
44096
- Local pid:
- pubs:44096
- Copyright date:
- 1993
Journal article
ANION RECOGNITION BY ACYCLIC REDOX-RESPONSIVE AMIDE-LINKED COBALTOCENIUM RECEPTORS
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