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Journal article

Capacitance spectroscopy: a versatile approach to resolving the redox density of states and kinetics in redox-active self-assembled monolayers.

Abstract:

Redox active self-assembled monolayers inherently possess both electrochemically addressable and polarizable components. The latter will contribute, with additional parasitic terms, to the iR drop effects within any form of electronic analysis, potentially distorting results. A capacitive analysis of such interfaces (Electroactive Monolayer Capacitance Spectroscopy), presented here, enables a clean mapping of both the thermodynamic and kinetic faradaic characteristics in a single experimental...

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Publication status:
Published

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Publisher copy:
10.1021/jp303700f

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
journal of physical chemistry. B More from this journal
Volume:
116
Issue:
30
Pages:
8822-8829
Publication date:
2012-08-01
DOI:
EISSN:
1520-5207
ISSN:
1520-6106
Language:
English
Pubs id:
pubs:348804
UUID:
uuid:0b3e09bf-61e5-4d77-ab1f-a6b350b69598
Local pid:
pubs:348804
Source identifiers:
348804
Deposit date:
2012-12-19

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